Supplementary Information for
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چکیده
The buffer used in the experiment was diluted from 1X Phosphate Buffer Saline (10g NaCl, 0.25g KCl, 1.8 g Na2HPO4, 0.3 g KH2PO4, 1000 ml H2O ) at pH=7.4 by a factor of 1/15. The resultant solution had an estimated conductivity of σ = 0.1441 S/m. The conductivity of the buffer was calculated from first principles using the electrophoretic mobilities of the ions (5.4 -8 m 2 /V.s for sodium ions and 8.1 -8 m 2 /V.s for potassium ions). The concentration of NaCl was roughly 11 mM, which is equivalent to 7.7 mM KCl based on the ratios of their electrophoretic mobilities. By choosing a relatively low ionic concentration, the device yields significant current increase while having negligible current decrease due to volume occupancy effect 1 .
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